There are many medications available that are designed to treat varying degrees and types of headaches. While some can be obtained easily from your local pharmacists, others require a prescription from a doctor.
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Fioricet is a prescription-only medication
Fioricet is a Schedule III drug under the Controlled Substance Act (CSA) meaning that it requires a prescription from a doctor to be used. Use of Fioricet without a prescription is considered abuse of the substance as it can have hazardous side effects, especially when abused with other substances such as alcohol or MAOIs.

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Speak to SAMSHAOver the counter alternatives to Fioricet
Fioricet is often only prescribed if the patient exhibits symptoms of tension headaches or migraines more than 10 times in a calendar month. If your symptoms are not as severe as this or you have yet to receive a prescription, the following over-the-counter pain medications could help:
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Naproxen
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Ibuprofen
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Advil
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Aleve
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Motrin
While these medications are available without a prescription (though some doctors will still prescribe them) it is important to check with a medical professional before taking them if you are on any other course of medication.